MySQL tutorial: ORD [EN]
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CerebroSQL

MySQL: 

ORD

Syntax:
ORD(str)

If the leftmost character of the string str is a multibyte character,
returns the code for that character, calculated from the numeric values
of its constituent bytes using this formula:

(1st byte code)
+ (2nd byte code * 256)
+ (3rd byte code * 256^2) ...

If the leftmost character is not a multibyte character, ORD() returns
the same value as the ASCII() function.

URL: https://dev.mysql.com/doc/refman/8.0/en/string-functions.html

Example

mysql> SELECT ORD('2');
-> 50

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